Hi Brandon, It appears that this issue is happening to me too.
We’re tracking an issue currently where if you have two authors on the blog, the Publicize settings from the author account that originally setup the connection to WordPress.com will always be used, as opposed to the settings of a second account that published the post.
This is exactly what is happening when I try to sync my client sites to their social pages. Can you help me reset these defaults so I can connect them to the right pages please? My outdoors client’s shrimp recipes are being posted to my professional profile pages. EEK! Thank you.
See the site – http://www.johninthewild.com for details.