Moving Hosts: Export Help

I am moving from one host to another and need some help with the data export so that when I reimport it I can just upload my site content as it was and poof, it is like nothing happened.

I don’t want to change the directory or database structure, just move the data.

Both sites have phpMyAdmin, I just don’t know what settings I need for the export and/or import to go smoothly.

Thanks
-DR