css file path for plugin modifcation

I am trying to modify the CSS for a slideshow plugin following instructions found here: http://wordpress.org/support/topic/plugin-slideshow-change-next-previous-button-colour?replies=3

But I can’t for the life of me figure out what I’m doing wrong. I suspect I am not using the correct filepath.

If my image is here: http://www.janineannett.com/wp-content/uploads/2014/06/next.png (for the “next” arrow, I want it to be black rather than white), what exact filepath do I need to use? Or perhaps it is some other issue? I can’t seem to get it to work.