Is there a way to place the tittle and add to cart button to display as a overlay on the product image? On the shop page
This is something that themes will implement, if they are designed that way. For example, take a look at our demo page for our Storefront child theme Galleria:
https://themes.woocommerce.com/galleria/product-category/menswear/
So while there’s no setting inside WooCommerce itself to do this, you should be able to find many themes that implement what you want. 🙂
Let us know if there’s anything else we can help with!