Permalinks only work when logged in

I get redirected to 404.php for all posts.
http://www.ecomomalliance.org

I have checked and .htaccess is writable

please help point me in the right direction, this site is going to be on t.v. very soon! thank you,

here is the .htaccess
# BEGIN WPSuperCache
<IfModule mod_rewrite.c>
RewriteEngine On
RewriteBase /
RewriteCond %{QUERY_STRING} !.*s=.*
RewriteCond %{HTTP_COOKIE} !^.*(comment_author_|wordpress|wp-postpass_).*$
RewriteCond %{HTTP:Accept-Encoding} gzip
RewriteCond %{DOCUMENT_ROOT}/wp-content/cache/supercache/%{HTTP_HOST}/$1/index.html.gz -f
RewriteRule ^(.*) /wp-content/cache/supercache/%{HTTP_HOST}/$1/index.html.gz [L]

RewriteCond %{QUERY_STRING} !.*s=.*
RewriteCond %{HTTP_COOKIE} !^.*(comment_author_|wordpress|wp-postpass_).*$
RewriteCond %{DOCUMENT_ROOT}/wp-content/cache/supercache/%{HTTP_HOST}/$1/index.html -f
RewriteRule ^(.*) /wp-content/cache/supercache/%{HTTP_HOST}/$1/index.html [L]
</IfModule>

# END WPSuperCache
# BEGIN WordPress
<IfModule mod_rewrite.c>
RewriteEngine On
RewriteBase /
RewriteCond %{REQUEST_FILENAME} !-f
RewriteCond %{REQUEST_FILENAME} !-d
RewriteRule . /index.php [L]
</IfModule>

# END WordPress